Direct hydroxylation of benzene to phenol in a microstructured Pd-based membrane reactor

The gas phase direct hydroxylation of benzene into phenol with hydrogen and oxygen, as initially described by Niwa in 2002, was realized in a newly developed double-membrane reactor. In the concept described by Niwa, a dense Pd membrane is used for the (safe) dosage of dissociated hydrogen species i...

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Bibliographic Details
Main Author: Bortolotto, Laurent (auth)
Format: Electronic Book Chapter
Language:English
Published: KIT Scientific Publishing 2011
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Summary:The gas phase direct hydroxylation of benzene into phenol with hydrogen and oxygen, as initially described by Niwa in 2002, was realized in a newly developed double-membrane reactor. In the concept described by Niwa, a dense Pd membrane is used for the (safe) dosage of dissociated hydrogen species into the tubular reaction zone, where it reacts with gas phase oxygen to form surface species capable of directly converting benzene into phenol in a single-step process.
Physical Description:1 electronic resource (XII, 244 p. p.)
ISBN:KSP/1000023388
9783866446953
Access:Open Access