Supramolecular Gold Chemistry From Atomically Precise Thiolate-Protected Gold Nanoclusters to Gold-Thiolate Nanostructures

• Other Authors: Antoine, Rodolphe (Editor)
• Format: Electronic Book Chapter
• Language: English
• Published: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute 2020
• Subjects: Technology: general issues; alloy; metal exchange; atomically precise; gold nanoclusters; thiolate; catenane; ion mobility; DFT calculations; gold nanocluster; cross-coupling; Ullmann hetero-coupling; Sonogashira coupling; Suzuki coupling; A3−coupling; catalytic mechanism; ligand removal; gold nanomaterials; electron dynamics; phonon dynamics; optical properties; Au70S20(PPh3)12 cluster; superatom network model; electronic structure; geometric structure; gold nanoparticles; graphene oxide; laser ablation; Au-GO nano-hybrid; coordination polymer structure; amino acids; template-assisted synthesis; fluorescence; Au(I)-thiolate; gold nanohybrid materials; 3-MBA/Au MPCs; TEA-HFIP; ESI-MS; HPLC-MS; bidentate binding; gold thiolate; coordination polymer; lamellar structure; luminescence; polymer composite; gold; cluster; catalyst; hydrogen evolution reaction; oxygen evolution reaction; oxygen reduction reaction; water splitting; fuel cells; ligand-protected; photoluminescence mechanism; metal nanoclusters; quantum confinement effect; ligand effect; p band intermediate state (PBIS); interface state; nanocatalysis; 6-aza-2-thio-thymine; protein; n/a
• Online Access: DOAB: download the publication; DOAB: description of the publication

This book is about supramolecular gold chemistry. This book provides a unique international forum aimed at covering a broad description of results involving the supramolecular chemistry of gold with a special focus on the gold-sulfur interface leading to hybrid materials ranging from gold-thiolate complexes to thiolate-protected gold nanoclusters and gold-thiolate supramolecular assemblies or nanoparticles. The role of thiolates on the structure and optical features of gold nanohybrid systems (ranging from plasmonic gold nanoparticles and fluorescent gold nanoclusters to self-assembled Au-containing thiolated coordination polymers) is highlighted in the 12 papers presented in this book.