Recent Advances in Iron Catalysis

Transition metal-catalyzed reactions play a key role in many transformations of synthetic organic chemistry. For most of these reactions, noble metals, for example, palladium, have been used as catalysts. Over the last two decades, more and more first row transition metals have been applied as catal...

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Other Authors: Knölker, Hans-Joachim (Editor)
Format: Electronic Book Chapter
Language:English
Published: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute 2020
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520 |a Transition metal-catalyzed reactions play a key role in many transformations of synthetic organic chemistry. For most of these reactions, noble metals, for example, palladium, have been used as catalysts. Over the last two decades, more and more first row transition metals have been applied as catalysts for organic reactions, with iron taking the center stage. The driving forces behind this development are not only the high costs for the noble metals but also their toxicity. Iron is the most abundant transition metal in the Earth's crust, and thus, it is considerably cheaper than the precious noble metals. Moreover, iron compounds are involved in many biological processes, and thus, iron exhibits a low toxicity. Because of this low toxicity, iron-catalyzed reactions are important for an environmentally benign sustainable chemistry. However, iron catalysts are not only investigated to replace noble metals; they offer many applications in synthesis beyond those of classical noble metal catalysts. Several articles of the present book emphasize the complementarity of iron-catalyzed reactions as compared to reactions catalyzed by noble metals. The book shows intriguing recent developments and the current standing of iron-catalyzed reactions as well as applications to organic synthesis. 
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650 7 |a Research & information: general  |2 bicssc 
653 |a iron 
653 |a cross-coupling 
653 |a aryl esters 
653 |a C-O activation 
653 |a Fe-catalysis 
653 |a Kumada cross-coupling 
653 |a iron complexes 
653 |a hydrogen transfer 
653 |a reductive amination 
653 |a alcohols 
653 |a amines 
653 |a decarbonylation 
653 |a alkylation 
653 |a spirocyclization 
653 |a aldehyde 
653 |a cinnamamide 
653 |a iron catalysis 
653 |a bis-(aryl)manganese 
653 |a alkenyl halides 
653 |a ate iron(II) complex 
653 |a asymmetric catalysis 
653 |a nitrogen ligand 
653 |a oxidative coupling 
653 |a BINOL synthesis 
653 |a carbene 
653 |a diazoalkane 
653 |a C-H functionalization 
653 |a catalysis 
653 |a borylation 
653 |a Iron 
653 |a C-H functionalisation 
653 |a pinacolborane 
653 |a photochemistry 
653 |a amidation 
653 |a iron(III) chloride 
653 |a amides 
653 |a esters 
653 |a solvent-free 
653 |a iron-catalysis 
653 |a carboazidation 
653 |a β-methyl scission 
653 |a radical 
653 |a DFT 
653 |a organic synthesis 
653 |a C-H activation 
653 |a C-C coupling 
653 |a α-alkenylation 
653 |a dehydrogenative coupling 
653 |a sustainability 
653 |a naphthidines 
653 |a fluorescence 
653 |a iron catalyst 
653 |a ATRP 
653 |a controlled radical polymerization 
653 |a external stimuli 
653 |a asymmetric transfer hydrogenation 
653 |a density functional theory 
653 |a bifunctional catalyst 
653 |a haloalkane coupling 
653 |a Grignard reagent 
653 |a FeI/FeII/FeIII mechanism 
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