Functional Coordination Polymers and Metal-Organic Frameworks

• Other Authors: Rossin, Andrea (Editor)
• Format: Electronic Book Chapter
• Language: English
• Published: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute 2021
• Subjects: Research & information: general; zirconium-based MOFs; water adsorption; ethanol adsorption; porous materials; adsorption heat pump; coordination polymer; MOF; CP; dimensionality control; Cu(II)-4,4'-bipyridine; dipyridil ligand; copper; metal-organic frameworks; solid sorbents; shaping; gas separation; gas storage; water harvesting; zirconium; metal-organic framework; post-synthetic modification; iridium catalysis; water oxidation; water splitting; thiazole; thiadiazole; coordination polymers; luminescence; cerium; terephthalic acid; spectroscopic characterization; adsorption; calorimetry; carbon dioxide; Ag(I) complexes; metal-organic coordination polymers; thermally activated delayed fluorescence; phosphorescence; pyrimidylphosphines; poly(azolate) spacers; 1,3-bis(1,2,4-triazol-4-yl)adamantane; zinc; cadmium; crystal structure; group 12 metals; 1H-indazole-6-carboxylic acid; photoluminescence properties; organometallic; coordination bonds; supramolecular chemistry; catalysis; n/a
• Online Access: DOAB: download the publication; DOAB: description of the publication

This book is a collection of contributions on the synthesis, characterization, and applications of Metal-Organic Frameworks (MOF) and Coordination Polymers (CP). Coordination Polymers (CP) and Metal-Organic Frameworks (MOF) are at the core of contemporary research on inorganic materials. The virtually infinite combination of their building blocks-inorganic metallic nodes (single ions or clusters) and organic polytopic linkers (polycarboxylates, bridging N-/S-/O-containing heterocycles)-generates solid air- and water-stable compounds. Interesting features from an applicative point of view are porosity, large surface area, and lattice flexibility (the "breathing" effect). These properties make them ubiquitous in several fields of materials science: gas storage and separation, luminescent sensing, heterogeneous catalysis, and magnetism.