Pengaruh Penambahan Paladium Terhadap Perilaku Thermal Amalgam Tembaga Tinggi Tipe Lathe Cut
<p>Effects of additing 1 percent (w/o) palladium (Pd) on the thermal behavior of a lathe cut type high copper amalgam (13 w/o copper) were studied. The identical alloys, with and without 1% Pd were fabricated. X-ray diffraction studies of the amalgams revealed the elimination of the γ<sub&g...
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Format: | Book |
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Faculty of Dentistry, Universitas Indonesia,
2015-09-01T00:00:00Z.
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Summary: | <p>Effects of additing 1 percent (w/o) palladium (Pd) on the thermal behavior of a lathe cut type high copper amalgam (13 w/o copper) were studied. The identical alloys, with and without 1% Pd were fabricated. X-ray diffraction studies of the amalgams revealed the elimination of the γ<sub>2</sub>-phase by Pd addition DSC thermogram of non-Pd containing amalgam indicated the existence of two γ<sub>1</sub>-phaseone with the transition temperature (endothermic peak) at 88<sup>◦</sup>C and the other at 109<sup>◦</sup>C. The thermogram data of the Pd containing amalgam showed an endothermic peak at 110.7<sup>◦</sup>C. The transition temperature of the n phase of the palladium containing amalgam is 4.9<sup>◦</sup>C lower than the transition temperature of the n phase of the non Pd containing amalgam. This result indicates that the n phase of the Pd containing amalgam includes more of Tin (Sn) than the non-Pd containing amalgam. The thermogravimetri diagram showed that the phase decomposition occurred at about 390<sup>◦</sup>C for the non-Pd containing amalgam and at about 410<sup>◦</sup>C for the Pd containing amalgam. It is concluded that the addition of 1% Pd into a lathe cut type of high copper amalgam (13%) could eliminate the formation of γ<sub>2</sub> phase as well as an unstable γ<sub>1</sub> phase, promoting strong mercury bonding to Silver.</p> |
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Item Description: | 1693-9697 2355-4800 10.14693/jdi.v9i2.681 |