Synthesis and Characterization of Mn(II), Co(II), Ni(II) and Cu(H) complexes with 1,1,2,2-tetrakis-(benzothiazolethio) ethylene and mercaptobenzothiazole salt
A new ligands l,l,2,2-tetrakis-(benzothiazolethio) ethylene (Li) and mercaptobenzothiazole potassium (L2) had been synthesized, investigated and used in the preparation of Mn*2, Co+2, Ni*2 and Cu+2 complexes. Also the reaction of the above complexes with 1,10-phenanthroline has been reported. The co...
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Format: | Book |
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College of Education for Pure Sciences,
2006-09-01T00:00:00Z.
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Summary: | A new ligands l,l,2,2-tetrakis-(benzothiazolethio) ethylene (Li) and mercaptobenzothiazole potassium (L2) had been synthesized, investigated and used in the preparation of Mn*2, Co+2, Ni*2 and Cu+2 complexes. Also the reaction of the above complexes with 1,10-phenanthroline has been reported. The complexes and adducts were characterized using IR and UV-visible spectroscopy, atomic absorption molar conductivity and magnetic moments measurements.<br /> Electronic spectra and magnetic measurement showed that some of the complexes have tetrahedral geometry, the other complexes and the adducts have an octahedral geometry. |
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Item Description: | 1812-125X 2664-2530 10.33899/edusj.2006.77525 |