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THE EFFECT OF SO42- SULPHATE ANIONS ON THE ULTRAFINE TITANIA NUCLEATION

We have proposed and experimentally tested a phenomenological model of SO<sub>4</sub><sup>2-</sup> sulphate anions effect on the titania nucleation during hydrolysis of titanium tetrachloride. Sulphate anions form the chelating bidentate complexes with primary [Ti(OH)<sub&...

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Main Authors: V. O. Kotsyubynsky (Author), I. F. Myronyuk (Author), B. K. Ostafiychuk (Author), V. L. Chelyadyn (Author), A. B. Hrubiak (Author), I. I. Hryhoruk (Author)
Format: Book
Published: Vasyl Stefanyk Precarpathian National University, 2016-07-01T00:00:00Z.
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Summary:We have proposed and experimentally tested a phenomenological model of SO<sub>4</sub><sup>2-</sup> sulphate anions effect on the titania nucleation during hydrolysis of titanium tetrachloride. Sulphate anions form the chelating bidentate complexes with primary [Ti(OH)<sub>h</sub>(OH<sub>2</sub>)<sub>6-h</sub>]<sup>(4-h)+</sup> with the influence on the next olation process and promotion of anatase phase nucleation.
Item Description:2311-0155
2413-2349
10.15330/jpnu.3.1.29-37

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