Kinetics and Mechanism of Chlorination of N-Acetylglycin by Chloramine-T In Acidic Medium
ABSTRACT<br /> The kinetics of chlorination of N-acetylglycin (AG) with sodium N-chloro -p- toluene sulphonamide (CAT) in presence of HCL has been studied at 318 oK. The reaction rate shows afirst -order dependence each on [CAT] and [H+] and zero order dependence on [AG]. The Variation of ioni...
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College of Education for Pure Sciences,
1999-11-01T00:00:00Z.
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| Summary: | ABSTRACT<br /> The kinetics of chlorination of N-acetylglycin (AG) with sodium N-chloro -p- toluene sulphonamide (CAT) in presence of HCL has been studied at 318 oK. The reaction rate shows afirst -order dependence each on [CAT] and [H+] and zero order dependence on [AG]. The Variation of ionic strength of the medium or chloride ion had no significant effect on the reaction rate. Addition of P-TSA is marginally affected the reaction rate. The rate increase with decreasing dielectric constant of the medium. The stiochiometry of the reaction was found 1:1 and the oxidation producte were identified. The thermodynamic parameters were computed. The mechanism proposed and the derived rate law were in agreement with the observed kinetics. |
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| Item Description: | 1812-125X 2664-2530 10.33899/edusj.1999.58805 |