Kinetics and Mechanism of Chlorination of N-Acetylglycin by Chloramine-T In Acidic Medium
ABSTRACT<br /> The kinetics of chlorination of N-acetylglycin (AG) with sodium N-chloro -p- toluene sulphonamide (CAT) in presence of HCL has been studied at 318 oK. The reaction rate shows afirst -order dependence each on [CAT] and [H+] and zero order dependence on [AG]. The Variation of ioni...
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College of Education for Pure Sciences,
1999-11-01T00:00:00Z.
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| 001 | doaj_c50f3b10e4bb4dfeb5c73791314fc9a6 | ||
| 042 | |a dc | ||
| 100 | 1 | 0 | |a Noor Saeed |e author |
| 245 | 0 | 0 | |a Kinetics and Mechanism of Chlorination of N-Acetylglycin by Chloramine-T In Acidic Medium |
| 260 | |b College of Education for Pure Sciences, |c 1999-11-01T00:00:00Z. | ||
| 500 | |a 1812-125X | ||
| 500 | |a 2664-2530 | ||
| 500 | |a 10.33899/edusj.1999.58805 | ||
| 520 | |a ABSTRACT<br /> The kinetics of chlorination of N-acetylglycin (AG) with sodium N-chloro -p- toluene sulphonamide (CAT) in presence of HCL has been studied at 318 oK. The reaction rate shows afirst -order dependence each on [CAT] and [H+] and zero order dependence on [AG]. The Variation of ionic strength of the medium or chloride ion had no significant effect on the reaction rate. Addition of P-TSA is marginally affected the reaction rate. The rate increase with decreasing dielectric constant of the medium. The stiochiometry of the reaction was found 1:1 and the oxidation producte were identified. The thermodynamic parameters were computed. The mechanism proposed and the derived rate law were in agreement with the observed kinetics. | ||
| 546 | |a AR | ||
| 546 | |a EN | ||
| 690 | |a kinetics | ||
| 690 | |a chlorination | ||
| 690 | |a n-acetylglycin | ||
| 690 | |a chloramine-t | ||
| 690 | |a acidic medium | ||
| 690 | |a Education | ||
| 690 | |a L | ||
| 690 | |a Science (General) | ||
| 690 | |a Q1-390 | ||
| 655 | 7 | |a article |2 local | |
| 786 | 0 | |n مجلة التربية والعلم, Vol 24, Iss 3, Pp 41-50 (1999) | |
| 787 | 0 | |n https://edusj.mosuljournals.com/article_58805_c1a3378b5723e80440f151196019c12c.pdf | |
| 787 | 0 | |n https://doaj.org/toc/1812-125X | |
| 787 | 0 | |n https://doaj.org/toc/2664-2530 | |
| 856 | 4 | 1 | |u https://doaj.org/article/c50f3b10e4bb4dfeb5c73791314fc9a6 |z Connect to this object online. |