The new paradigm in thermodynamic formulation of electrolytic systems - A review

<p>The general property of electrolytic systems in aqueous media is presented. The linear combination f12 = 2∙f(O) - f(H) of elemental balances: f1 = f(H) for Y1 = H and f2 = f(O) for Y2 = O, is put in context with charge balance (f0 = ChB) and other elemental and/or core balances fk = f(Yk) (...

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Main Authors: Anna M Michałowska-Kaczmarczyk (Author), Tadeusz Michałowski (Author)
Format: Book
Published: Archive of Biomedical Science and Engineering - Peertechz Publications, 2019-08-12.
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042 |a dc 
100 1 0 |a Anna M Michałowska-Kaczmarczyk  |e author 
700 1 0 |a Tadeusz Michałowski  |e author 
245 0 0 |a The new paradigm in thermodynamic formulation of electrolytic systems - A review 
260 |b Archive of Biomedical Science and Engineering - Peertechz Publications,   |c 2019-08-12. 
520 |a <p>The general property of electrolytic systems in aqueous media is presented. The linear combination f12 = 2∙f(O) - f(H) of elemental balances: f1 = f(H) for Y1 = H and f2 = f(O) for Y2 = O, is put in context with charge balance (f0 = ChB) and other elemental and/or core balances fk = f(Yk) (k=3,...,K) related to the system in question It is stated that f12 is (a) linearly independent on f0,f3,...,fK for a redox system, or is (b) linearly dependent on f0,f3,...,fK when related to a non-redox system. The balance f12 = 2∙f(O) - f(H) is the primary form of generalized electron balance (GEB), completing the set of equations needed for quantitative description of electrolytic redox systems, f12 = pr-GEB.</p> 
540 |a Copyright © Anna M Michałowska-Kaczmarczyk et al. 
546 |a en 
655 7 |a Review Article  |2 local 
856 4 1 |u https://doi.org/10.17352/abse.000013  |z Connect to this object online.