A proposal on a catalyst for the reaction methane + water => methanol + hydrogen

<p>Based on the concepts and vocabulary of the SET model of catalysis a discussion is performed on what properties should characterize a catalyst promoting a reaction such as the one in the title, i.e., the production of methanol from methane in a non-oxidative environment. It is found that th...

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Autor principal: Ragnar Larsson (Autor)
Formato: Livro
Publicado em: Open Journal of Chemistry - Peertechz Publications, 2021-01-05.
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100 1 0 |a Ragnar Larsson  |e author 
245 0 0 |a A proposal on a catalyst for the reaction methane + water => methanol + hydrogen 
260 |b Open Journal of Chemistry - Peertechz Publications,   |c 2021-01-05. 
520 |a <p>Based on the concepts and vocabulary of the SET model of catalysis a discussion is performed on what properties should characterize a catalyst promoting a reaction such as the one in the title, i.e., the production of methanol from methane in a non-oxidative environment. It is found that the n1 vibration of water (3652 cm-1 ) and the ny4 vibration of methane (1306 cm-1) interact in resonance. </p><p>This means that 1306/3652 = 0.3576 whereas 5:14 = 0.3571. The difference between these two ratios is thus 0.0005. One notes that both frequency-values contain a factor of 1306/5 = 261 cm-1. The conclusion is that also the catalyst must take part in and promote that resonance, containing the same factor, 261 cm-1.</p> 
540 |a Copyright © Ragnar Larsson et al. 
546 |a en 
655 7 |a Research Article  |2 local 
856 4 1 |u https://doi.org/10.17352/ojc.000022  |z Connect to this object online.