Water-based immobilized Ag-doped TiO₂ photocatalyst for photocatalytic degradation of RR4 dye / Nureel Imanina Abdul Ghani ... [et al.]

This study used water-based preparation of immobilised Ag-TiO2 using the DSAT technique to avoid solvent interference of Ag-TiO2 photocatalytic performance. The preparation of Ag-TiO2 was conducted via the photodeposition method with silver nitrate (AgNO3) as Ag precursor at various ratios of Ag dop...

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Main Authors: Abdul Ghani, Nureel Imanina (Author), Rosli, Muhammad Afiq (Author), Hamzah, Siti Raihan (Author), Natar, Nadiah Sabihah (Author), Nazeri, Nur Syazana (Author), Ab Aziz, Syahirul Ikhwan (Author), Mohamad, Sarina (Author), Wan Ismail, Wan Izhan Nawawi (Author)
Format: Book
Published: UiTM Press, 2022-06.
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100 1 0 |a Abdul Ghani, Nureel Imanina  |e author 
700 1 0 |a Rosli, Muhammad Afiq  |e author 
700 1 0 |a Hamzah, Siti Raihan  |e author 
700 1 0 |a Natar, Nadiah Sabihah  |e author 
700 1 0 |a Nazeri, Nur Syazana  |e author 
700 1 0 |a Ab Aziz, Syahirul Ikhwan  |e author 
700 1 0 |a Mohamad, Sarina  |e author 
700 1 0 |a Wan Ismail, Wan Izhan Nawawi  |e author 
245 0 0 |a Water-based immobilized Ag-doped TiO₂ photocatalyst for photocatalytic degradation of RR4 dye / Nureel Imanina Abdul Ghani ... [et al.] 
260 |b UiTM Press,   |c 2022-06. 
500 |a https://ir.uitm.edu.my/id/eprint/63178/1/63178.pdf 
520 |a This study used water-based preparation of immobilised Ag-TiO2 using the DSAT technique to avoid solvent interference of Ag-TiO2 photocatalytic performance. The preparation of Ag-TiO2 was conducted via the photodeposition method with silver nitrate (AgNO3) as Ag precursor at various ratios of Ag dopant to TiO2. The immobilisation of Ag-TiO2 was prepared via water-based immobilisation using the DSAT method, and XRD and FESEM-EDX characterised the obtained photocatalyst. The photocatalytic performance of Ag-TiO2 was measured by photocatalytic degradation of Reactive Red 4 (RR4) dye. The optimum photocatalytic performance of suspension mode Ag-TiO2 was obtained at 3 % of Ag-TiO2. Sample 3 % Ag-TiO2 was applied under immobilisation mode with complete degradation of 30 mg/L RR4 dye achieved within 60 min under 55 W fluorescent lamp irradiation. It is 36 % faster compared to immobilised, unmodified TiO2. The acquired results from FESEM-EDX indicated the presence of 0.6 % Ag on the Ag-TiO2 photocatalyst sample. The photodegradation rate of immobilized 3 % Ag-TiO2 sample under different solvents has shown the different values among all where it was 0.096 > 0.037 > 0.029 > 0.029 > 0.025 min-1 for water-base, ethanol, methanol, dichloromethane and acetone respectively. Thus, the solvents can influence the photocatalytic performance of the immobilised 3 % Ag-TiO2 photocatalyst by molecular interference between Ag-doped in TiO2. The water-based immobilised 3 % Ag-TiO2 sample also has a sustainable performance where the photocatalytic activities are comparable to 10 cycles. 
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