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Organic Chemistry with a Biological Emphasis
Published 2016Table of Contents: “…Chapter 1: Introduction to organic structure and bonding, part I -- Section 1: Drawing organic structures -- Section 2: Functional groups and organic nomenclature -- Section 3: Structures of some important classes of biological molecules -- Chapter 2: Introduction to organic structure and bonding, part II -- Section 1: Covalent bonding in organic molecules -- Section 2: Molecular orbital theory -- Section 3: Resonance -- Section 4: Non-covalent interactions -- Section 5: Physical properties of organic compounds -- Chapter 3: Conformation and Stereochemistry -- Section 1: Conformations of open-chain organic molecules -- Section 2: Conformations of cyclic organic molecules -- Section 3: Chirality and stereoisomers -- Section 4: Labeling chiral centers -- Section 5: Optical activity -- Section 6: Compounds with multiple chiral centers -- Section 7: Meso compounds -- Section 8: Fischer and Haworth projections -- Section 9: Stereochemistry of alkenes -- Section 10: Stereochemistry in biology and medicine -- Section 11: Prochirality -- Chapter 4: Structure determination part I - Infrared spectroscopy, UV-visible spectroscopy, and mass spectrometry -- Section 1: Mass Spectrometry -- Section 2: Introduction to molecular spectroscopy -- Section 3: Infrared spectroscopy -- Section 4: Ultraviolet and visible spectroscopy -- Chapter 5: Structure determination part II - Nuclear magnetic resonancespectroscopy -- Section 1: The origin of the NMR signal -- Section 2: Chemical equivalence -- Section 3: The 1H-NMR experiment -- Section 4: The basis for differences in chemical shift -- Section 5: Spin-spin coupling -- Section 6: 13C-NMR spectroscopy -- Section 7: Solving unknown structures -- Section 8: Complex coupling in 1H-NMR spectra -- Section 9: Other applications of NMR -- Chapter 6: Overview of organic reactivity -- Section 1: A first look at some organic reaction mechanisms -- Section 2: A quick review of thermodynamics and kinetics -- Section 3: Catalysis -- Section 4: Comparing biological reactions to laboratory reactions -- Chapter 7: Acid-base reactions -- Section 1: Acid-base reactions -- Section 2: Comparing the acidity and basicity of organic functional groups– the acidityconstant -- Section 3: Structural effects on acidity and basicity -- Section 4: Acid-base properties of phenols -- Section 5: Acid-base properties of nitrogen-containing functional groups -- Section 6: Carbon acids -- Section 7: Polyprotic acids -- Section 8: Effects of enzyme microenvironment on acidity and basicity -- Chapter 8: Nucleophilic substitution reactions -- Section 1: Two mechanistic models for nucleophilic substitution -- Section 2: Nucleophiles -- Section 3: Electrophiles -- Section 4: Leaving groups -- Section 5: SN1 reactions with allylic electrophiles -- Section 6: SN1 or SN2? …”
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