Spin-Crossover Complexes

• 1. autor: Kazuyuki Takahashi (Ed.) (auth)
• Format: Elektroniczne Rozdział
• Język: angielski
• Wydane: MDPI - Multidisciplinary Digital Publishing Institute 2018
• Hasła przedmiotowe: Chemistry; Stimulus-induced Spin Transition; Spin-Crossover (SCO); Crystal Engineering of SCO and related complexes; Valence Tautomerism; Multifunctionality of SCO and related complexes; Charge-transfer-induced Spin Transition; Ligand-driven Spin-state Conversion
• Dostęp online: DOAB: download the publication; DOAB: description of the publication

The spin-crossover (SCO) phenomenon originates from the intrinsic bistability of the d-electron configuration, created by the competition between ligand-field splitting and spin-pairing energies in a first coordination sphere of transition metal ions. Since Cambi's visionary finding of the SCO...