Synthesis and Applications of New Spin Crossover Compounds

• Main Author: Kitazawa, Takafumi (auth)
• Format: Electronic Book Chapter
• Language: English
• Published: MDPI - Multidisciplinary Digital Publishing Institute 2019
• Subjects: n/a; hexadentate ligand; X-ray diffraction; structural disorder; lattice energy; 2-bis(4-pyridyl)ethane; thermal hysteresis; optical conductivity spectrum; spin-state crossover; solvate; single crystal; spin-crossover transition; spin-crossover; cobalt oxide; amorphous; metal dithiolene complexes; qsal ligand; impurity effect; 3-triazole; intermolecular interactions; spin crossover; hydrogen bonding; 1; 2; optical microscopy; supramolecular coordination polymer; paramagnetic ligand; magnetic susceptibility; high spin; [Fe(III)(3-OMesal2-trien)]+; aminoxyl; cobalt(II) ion; mosaicity; Fe(III) coordination complexes; nitroxides; C-H···? interactions; Fe(II); dithiooxalato ligand; dinuclear triple helicate; coordination polymers; magnetization; spiral structure; magnetostructural correlations; charge-transfer phase transition; structure phase transition; magnetic properties; spin polaron; substitution of 3d transition metal ion; iron(II) complexes; X-ray absorption spectroscopy; coordination complexes; crystal engineering; fatigability; soft X-ray induced excited spin state trapping; spin transition; dipyridyl-N-alkylamine ligands; coordination polymer; iron (II); iron mixed-valence complex; chiral propeller structure; spin cross-over (SCO); EPR spectroscopy; Cu(II) complexes; solvent effects; ferromagnetism; SQUID; LIESST effect; low spin (LS); 57Fe Mössbauer spectroscopy; dielectric response; iron(II); hetero metal complex; atropisomerism; switch; Schiff base; counter-anion; DFT calculation; Fe(III) complex; Fe(II) complex; high spin (HS); reaction diffusion; thermochromism; supramolecular isomerism; phase transition; magnetic transition; mononuclear; [Au(dmit)2]?; UV-Vis spectroscopy; phase transitions; ?-? interactions; [Au(dddt)2]?; crystal structure; linear pentadentate ligand; ion-pair crystals
• Online Access: DOAB: download the publication; DOAB: description of the publication

The crystal chemistry of spin crossover (SCO) behavior in coordination compounds can potentially be in association with smart materials-promising materials for applications as components of memory devices, displays, sensors and mechanical devices and, especially, actuators, such as artificial muscle...