Nitro Compounds and Their Derivatives in Organic Synthesis

• Övriga skapare: Nishiwaki, Nagatoshi (Utgivare, redaktör, sammanställare)
• Materialtyp: Elektronisk Bokavsnitt
• Språk: engelska
• Publicerad: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute 2020
• Ämnen: Research & information: general; nitro; pyridone; 1-methyl-2-quinolone; cycloaddition; direct functionalization; perylenediimide; nitro group; organic materials; Phenacylation of beta-nitropyridin-2-ones; 8-nitro-5-RO-indolizines; oxazole-pyrrole ring transformation; conjugate addition; dihydrofuran; 1,3-dicarbonyl compound; enolate; isoxazoline N-oxide; nitroketone; nitronate; nucleophilic substitution; nitropyridines; isoxazolo[4,3-b]pyridines; 1,4-dihydropyridines; nucleophilic addition; Diels-Alder reaction; dearomatization; hexapyrrolohexaazacoronene; nitration; SNAr substitution; ICT character; aromaticity; C-H functionalization; total synthesis; pyrrolidines; anchimeric assistance; epimerization; PDE4 inhibitors; 1,3-Dipole; electron-withdrawing ability; electrophilicity; nucleophilicity
• Länkar: DOAB: download the publication; DOAB: description of the publication

Nitro chemistry plays an important role in organic synthesis to construct new frameworks. This is due to the diverse properties of the nitro group. The strong electron-withdrawing ability of the nitro group reduces the electron density of the scaffold, facilitating reactions with nucleophiles or ele...