Nitro Compounds and Their Derivatives in Organic Synthesis

• Другие авторы: Nishiwaki, Nagatoshi (Редактор)
• Формат: Электронный ресурс Глава книги
• Язык: английский
• Опубликовано: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute 2020
• Предметы: Research & information: general; nitro; pyridone; 1-methyl-2-quinolone; cycloaddition; direct functionalization; perylenediimide; nitro group; organic materials; Phenacylation of beta-nitropyridin-2-ones; 8-nitro-5-RO-indolizines; oxazole-pyrrole ring transformation; conjugate addition; dihydrofuran; 1,3-dicarbonyl compound; enolate; isoxazoline N-oxide; nitroketone; nitronate; nucleophilic substitution; nitropyridines; isoxazolo[4,3-b]pyridines; 1,4-dihydropyridines; nucleophilic addition; Diels-Alder reaction; dearomatization; hexapyrrolohexaazacoronene; nitration; SNAr substitution; ICT character; aromaticity; C-H functionalization; total synthesis; pyrrolidines; anchimeric assistance; epimerization; PDE4 inhibitors; 1,3-Dipole; electron-withdrawing ability; electrophilicity; nucleophilicity
• Online-ссылка: DOAB: download the publication; DOAB: description of the publication

Nitro chemistry plays an important role in organic synthesis to construct new frameworks. This is due to the diverse properties of the nitro group. The strong electron-withdrawing ability of the nitro group reduces the electron density of the scaffold, facilitating reactions with nucleophiles or ele...