Carbon Ligands From Fundamental Aspects to Applications

• Other Authors: Canac, Yves (Editor)
• Format: Electronic Book Chapter
• Language: English
• Published: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute 2021
• Subjects: Research & information: general; carbenes; ylides; DFT calculations; electronic structure; catalysis; ligands; structure-activity relationship; NHC; nanoparticle; calixarene; palladium catalyst; Suzuki-Miyaura reaction; amino-acids; water; carbon ligand; amide; negative charge; phosphonium ylide; oxide; pincer; metathesis; ruthenium; nitro catalysts; NHC ligands; olefins; selenonium ylides; selenonium salts; chirality; stereogenic selenium atom; asymmetric synthesis; optical resolution; reactivity; malaria; Plasmodium falciparum; gold; NHC-ligands; hybrid molecules; drug resistance; N-heterocyclic carbene; platinum; metal complexes; 195Pt NMR; N-heterocyclic carbenes; imidazole; spectroscopy; X-ray; mercury(II) complex; T-shaped; carbodiphosphorane; phosphorus ylides; pincer ligands; coordination chemistry; Cu(I) complex; photoluminescence; titanium; hafnium; copolymerization of epoxide with CO2; density functional theory; natural bond orbitals; aromaticity; ion pairs; alkali metals; tropylidenyl ions; cyclooctatetraene ions; rhodium; electron paramagnetic resonance (EPR) spectroscopy; density functional theory (DFT); electrochemistry; carbone complexes; carbido complexes; transition metal complexes; chemical bonding; pincer ligand; macrocycle; lithium; potassium; intramolecular C-H activation; dehydrogenation; carbone; ligand; germylene; coordination; ylide; n/a
• Online Access: DOAB: download the publication; DOAB: description of the publication

Homogeneous catalysis owes its success, in large part, to the development of a wide range of ligands with well-defined electronic and steric properties, which have thus made it possible to adjust the behavior of many organometallic complexes. However, ligands used in catalysis have long been centere...