(+)/(−)-Gerbeloid A, a pair of unprecedented coumarin-based polycyclic meroterpenoid enantiomers from Gerbera piloselloides: Structural elucidation, semi-synthesis, and lipid-lowering activity

• Auteurs principaux: Chenxu Zhao (Auteur), Jingrong Li (Auteur), Yue Hu (Auteur), Lingyu Li (Auteur), Meng Yu (Auteur), Yunfeng Huang (Auteur), Tao Zhang (Auteur), Hai Shang (Auteur), Zhongmei Zou (Auteur)
• Format: Livre
• Publié: Elsevier, 2024-06-01T00:00:00Z.
• Sujets: article
• Accès en ligne: Connect to this object online.

A pair of coumarin-based polycyclic meroterpenoid enantiomers (+)/(−)-gerbeloid A [(+)-1a and (−)-1b] were isolated from the medicinal plant Gerbera piloselloides, which have a unique caged oxatricyclo [4.2.2.03,8] decene scaffold. Their planar and three-dimensional structures were exhaustively char...