Increased efficiency in biomimetic Lewis acid-base pair catalyzed monoacylation of diols by acyl phosphate monoesters
Acyl phosphate monoesters are biomimetic acylation reagents that require coordination to metal ions to react with cis-diol substrates in water. With lanthanide catalysts, outcomes are compromised by (1) the competitive lanthanide-promoted hydrolysis of the acyl phosphate reagents as well as by (2) t...
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| Format: | Book |
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Canadian Science Publishing,
2017-09-01T00:00:00Z.
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