Tricarbocyclic core formation of tyrosine-decahydrofluorenes implies a three-enzyme cascade with XenF-mediated sigmatropic rearrangement as a prerequisite

Tyrosine-decahydrofluorene derivatives feature a fused [6.5.6] tricarbocyclic core and a 13-membered para-cyclophane ether. Herein, we identified new xenoacremones A, B, and C (1−3) from the fungal strain Xenoacremonium sinensis ML-31 and elucidated their biosynthetic pathway using gene deletion in...

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Main Authors: Zhiguo Liu (Author), Wei Li (Author), Peng Zhang (Author), Jie Fan (Author), Fangbo Zhang (Author), Caixia Wang (Author), Shuming Li (Author), Yi Sun (Author), Shilin Chen (Author), Wenbing Yin (Author)
Format: Book
Published: Elsevier, 2021-11-01T00:00:00Z.
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