Syntheses of Au(III) and Au(I) Complexes of 3,4,5,6-Tetraphenyl-2,2´-bipyridine
Treatment of the ligand 3,4,5,6-tetraphenyl-2,2´-bipyridine (LH) VIII with HAuCl4 in acetonitrile afforded the cyclometallated square-planar Au(III) complex [LAuCl]ClO4 (7) containing the anionic tridentate (N∧N∧C) ligand, via orthometallation. Treatment of (7) with 4-dimetylaminopyridine (DMAP) and...
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| Materiálatiipa: | Girji |
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The Open University of Sri Lanka,
2023-09-01T00:00:00Z.
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